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・ 2-Hydroxymuconate semialdehyde
・ 2-hydroxymuconate tautomerase
・ 2-Hydroxymuconate-6-semialdehyde dehydrogenase
・ 2-hydroxymuconate-semialdehyde hydrolase
・ 2-hydroxyphytanoyl-CoA lyase
・ 2-hydroxypropyl-CoM lyase
・ 2-hydroxypyridine 5-monooxygenase
・ 2-hydroxyquinoline 5,6-dioxygenase
・ 2-hydroxyquinoline 8-monooxygenase
・ 2-Imidazoline
・ 2-iminoacetate synthase
・ 2-Iminothiolane
・ 2-in-1 PC
・ 2-inch Medium Mortar
・ 2-inch mortar
2-Iodobenzoic acid
・ 2-Iodoxybenzoic acid
・ 2-Isopropyl-5-methyl-1-(2,6-dihydroxy-4-nonylphenyl)cyclohex-1-ene
・ 2-isopropylmalate synthase
・ 2-Ketoarginine methyltransferase
・ 2-lane expressway
・ 2-MDP
・ 2-Me-DET
・ 2-Mercaptoethanol
・ 2-Mercaptoindole
・ 2-Mercaptopyridine
・ 2-meter band
・ 2-Methoxy-4-vinylphenol
・ 2-Methoxy-6-polyprenyl-1,4-benzoquinol methylase
・ 2-Methoxyamphetamine


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2-Iodobenzoic acid : ウィキペディア英語版
2-Iodobenzoic acid

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2-Iodobenzoic acid, or ''o''-iodobenzoic acid, is an organic compound with the formula IC6H4COOH. The synthesis of 2-iodobenzoic acid ''via'' the diazotization of anthranilic acid is commonly performed in university organic chemistry labs. One of its most common uses is as a precursor for the preparation of IBX and Dess–Martin periodinane, both used as mild oxidants.
== Synthesis ==
2-Iodobenzoic acid can be synthesized ''via'' a Sandmeyer reaction consisting of the diazotization of anthranilic acid followed by a diazo replacement. First anthranilic acid is treated with nitrous acid in order to convert the amino group into the diazo group. The diazo group is ejected, yielding a carbocation which is then attacked by the highly nucleophilic I anion.
The nitrous acid is usually generated ''in situ'' from sodium nitrite.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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